Coexistence of Solvated Electrons and Solvent Valence Anions in Negatively Charged Acetonitrile Clusters, (CH3CN)n- (n = 10-100)

Masaaki Mitsui, Naoto Ando, Shinsuke Kokubo, Atsushi Nakajima, Koji Kaya

研究成果: Article査読

45 被引用数 (Scopus)

抄録

The coexistence of solvated electrons and solvent valence anions in negatively charged acetonitrile clusters, (CH3CN)- n (n=10-100) was discussed. The distinctly different nature of the anions were found to be revealed by hole-burning-type photoelectron spectroscopy. The analysis showed that the coexistence was due to the closely lying nature of their anionic state at just the number of solvent molecules sufficient to almost to complete the first solvation layer.

本文言語English
論文番号153002
ページ(範囲)1530021-1530024
ページ数4
ジャーナルPhysical review letters
91
15
出版ステータスPublished - 2003 10 10

ASJC Scopus subject areas

  • 物理学および天文学(全般)

フィンガープリント

「Coexistence of Solvated Electrons and Solvent Valence Anions in Negatively Charged Acetonitrile Clusters, (CH<sub>3</sub>CN)<sub>n</sub><sup>-</sup> (n = 10-100)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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