Coexistence of two different anion states in polyacene nanocluster anions

Masaaki Mitsui, Shinsuke Kokubo, Naoto Ando, Yukino Matsumoto, Atsushi Nakajima, Koji Kaya

研究成果: Article査読

14 被引用数 (Scopus)

抄録

The coexistence of two types of anion sates in nanometer-scale polyacene cluster anions, was analyzed. Nanoclusters of naphthalene and anthracene having single excess electron were synthesized in the gas-phase. The photoelectron spectra of size-selected cluster anions containing 2 to 100 molecules exhibited rigid 'crystal-like' cluster anion in which surrounding neutral molecules reorganize around the charge core. The results show that two anion states appear to correlate to negative polaronic states formed in corresponding crystals.

本文言語English
ページ(範囲)7553-7556
ページ数4
ジャーナルJournal of Chemical Physics
121
16
DOI
出版ステータスPublished - 2004 10 22

ASJC Scopus subject areas

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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