Construction of cyclohepta[ b ]indoles via platinum-catalyzed intermolecular formal [4+3]-cycloaddition reaction of α,β-unsaturated carbene complex intermediates with siloxydienes

Hiroyuki Kusama, Hideyuki Sogo, Kodai Saito, Takuya Suga, Nobuharu Iwasawa

研究成果: Article査読

26 被引用数 (Scopus)

抄録

Platinum(II)-catalyzed intermolecular formal [4+3]-cycloaddition reaction of α,β-unsaturated carbene complex intermediates with siloxydienes proceeded under mild conditions to give cyclohepta[b]indole derivatives in good yield. The reaction was found to proceed via 1,2-alkyl shift of the carbene complex intermediates obtained by [4+2]-cycloaddition reaction of the unsaturated carbenes with dienes.

本文言語English
論文番号ST-2013-U0220-L
ページ(範囲)1364-1370
ページ数7
ジャーナルSynlett
24
11
DOI
出版ステータスPublished - 2013
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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