Construction of cyclohepta[ b ]indoles via platinum-catalyzed intermolecular formal [4+3]-cycloaddition reaction of α,β-unsaturated carbene complex intermediates with siloxydienes

Hiroyuki Kusama, Hideyuki Sogo, Kodai Saito, Takuya Suga, Nobuharu Iwasawa

研究成果: Article

24 引用 (Scopus)

抜粋

Platinum(II)-catalyzed intermolecular formal [4+3]-cycloaddition reaction of α,β-unsaturated carbene complex intermediates with siloxydienes proceeded under mild conditions to give cyclohepta[b]indole derivatives in good yield. The reaction was found to proceed via 1,2-alkyl shift of the carbene complex intermediates obtained by [4+2]-cycloaddition reaction of the unsaturated carbenes with dienes.

元の言語English
記事番号ST-2013-U0220-L
ページ(範囲)1364-1370
ページ数7
ジャーナルSynlett
24
発行部数11
DOI
出版物ステータスPublished - 2013 5 16
外部発表Yes

ASJC Scopus subject areas

  • Organic Chemistry

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