Construction of cyclohepta[ b ]indoles via platinum-catalyzed intermolecular formal [4+3]-cycloaddition reaction of α,β-unsaturated carbene complex intermediates with siloxydienes

Hiroyuki Kusama, Hideyuki Sogo, Kodai Saito, Takuya Suga, Nobuharu Iwasawa

研究成果: Article

22 引用 (Scopus)

抄録

Platinum(II)-catalyzed intermolecular formal [4+3]-cycloaddition reaction of α,β-unsaturated carbene complex intermediates with siloxydienes proceeded under mild conditions to give cyclohepta[b]indole derivatives in good yield. The reaction was found to proceed via 1,2-alkyl shift of the carbene complex intermediates obtained by [4+2]-cycloaddition reaction of the unsaturated carbenes with dienes.

元の言語English
記事番号ST-2013-U0220-L
ページ(範囲)1364-1370
ページ数7
ジャーナルSynlett
24
発行部数11
DOI
出版物ステータスPublished - 2013
外部発表Yes

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Cycloaddition
Platinum
Derivatives
cyclohepta(b)indole
carbene

ASJC Scopus subject areas

  • Organic Chemistry

これを引用

Construction of cyclohepta[ b ]indoles via platinum-catalyzed intermolecular formal [4+3]-cycloaddition reaction of α,β-unsaturated carbene complex intermediates with siloxydienes. / Kusama, Hiroyuki; Sogo, Hideyuki; Saito, Kodai; Suga, Takuya; Iwasawa, Nobuharu.

:: Synlett, 巻 24, 番号 11, ST-2013-U0220-L, 2013, p. 1364-1370.

研究成果: Article

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AU - Sogo, Hideyuki

AU - Saito, Kodai

AU - Suga, Takuya

AU - Iwasawa, Nobuharu

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KW - platinum

KW - siloxy diene

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