TY - JOUR
T1 - Coordination structure and magnetic property of poly(pyridilenemethylidenenitriloiron)s
AU - Nishide, Hiroyuki
AU - Yoshioka, Naoki
AU - Tsuchida, Eishun
AU - Inoue, Hidenari
PY - 1989/1/30
Y1 - 1989/1/30
N2 - Poly[bis(2,6‐pyridinediylmethylidenenitrilohexamethylenenitrilomethylidene)iron sulfate] was said to be a ferromagnetic compound by earlier investigators. This polymer and its derivatives are carefully reprepared and their unusual magnetic property is reinvestigated spectroscopically. The counter anion species and spacer length of the polymers affect their coordination structure and magnetism. Mössbauer spectroscopy and x‐ray diffractometry on the polymers indicate that their unusual magnetic property is caused by the ferromagnetic iron oxide slightly formed in the polymers.
AB - Poly[bis(2,6‐pyridinediylmethylidenenitrilohexamethylenenitrilomethylidene)iron sulfate] was said to be a ferromagnetic compound by earlier investigators. This polymer and its derivatives are carefully reprepared and their unusual magnetic property is reinvestigated spectroscopically. The counter anion species and spacer length of the polymers affect their coordination structure and magnetism. Mössbauer spectroscopy and x‐ray diffractometry on the polymers indicate that their unusual magnetic property is caused by the ferromagnetic iron oxide slightly formed in the polymers.
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U2 - 10.1002/pola.1989.080270210
DO - 10.1002/pola.1989.080270210
M3 - Article
AN - SCOPUS:0024303225
SN - 0887-624X
VL - 27
SP - 497
EP - 505
JO - Journal of Polymer Science, Part A: Polymer Chemistry
JF - Journal of Polymer Science, Part A: Polymer Chemistry
IS - 2
ER -