Copper(II) 2-thiopheneglyoxylate adducts with pyridine derivatives

Kazuyuki Nakasa, Hiroo Nakagawa, Yoshiyuki Kani, Masanobu Tsuchimoto, Shigeru Ohba

研究成果: Article査読

3 被引用数 (Scopus)

抄録

In the crystals of trans-bis(pyridine-N)bis(2-thiopheneglyoxylato-O1,O 2)copper(II), [Cu(C6H3O3S)2(C5H 5N)2], there is a mononuclear CuII complex molecule. In the crystal of catena-poly[[[bis(2-thiopheneglyoxylato-O1,O 2)copper(II)]-μ-(2-thiopheneglyoxylato-O1:O 1′,O 2)-[bis(3-methylpyridine-N)copper(II)]-μ-(2-thiopheneglyoxylato- O1,O2:O1′)] monohydrate], {[Cu2(C6H3O3S)4-(C 6H7N)2]·H2O}n, there is a zigzag polymer chain where the CuII atoms are bridged by the thiopheneglyoxylate ions. In the crystal of cis-bis(4-methylpyridine-N)bis(2-thiopheneglyoxylato-O1,O 2)copper(II), [Cu-(C6H3O3S)2(C6H 7N)2], there is a mononuclear CuII complex. The coordination geometry around the Cu atoms is distorted octahedral. Each thiopheneglyoxylate ion adopts a flattened structure and forms a five-membered chelate ring with the Cu atom.

本文言語English
ページ(範囲)513-517
ページ数5
ジャーナルActa Crystallographica Section C: Crystal Structure Communications
55
4
DOI
出版ステータスPublished - 1999 4月 15

ASJC Scopus subject areas

  • 生化学、遺伝学、分子生物学(全般)

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