抄録
A crystal structure determination of Cu(phpyH)ClClO4 • CH3OH revealed that the protonated phenolic oxygen atom lies at the apex of a square pyramidal CuN4O arrangement with Cu(II) - O(phenolic) distances of 2.46 and 2.57 Å; this is a novel copper(II) model compound for galactose oxidase where the Cu(II)-phenolic oxygen (Tyrosine-495) distance is rather long, 2.69 Å, and the present results may provide chemical evidence for possible participation of Tyrosine-495 in the oxidation of galactose.
本文言語 | English |
---|---|
ページ(範囲) | 1637-1642 |
ページ数 | 6 |
ジャーナル | Polyhedron |
巻 | 17 |
号 | 10 |
DOI | |
出版ステータス | Published - 1998 |
ASJC Scopus subject areas
- 物理化学および理論化学
- 無機化学
- 材料化学