De Novo highly stereocontrolled synthesis of 2,6-dideoxy-C-3-branched carbohydrates by use of 2,6-anhydro-2-thio sugar: l-cladinose and its C-3 epimer

Kazunobu Toshima, Takehito Yoshida, Satsuki Mukaiyama, Kuniaki Tatsuta

研究成果: Article査読

8 被引用数 (Scopus)

抄録

L-Cladinose (1) and its C-3 epimer 2 were synthesized through a highly stereoselective addition of methyl anion to the C-3 carbonyl groups of α-anomer 9 and β-anomer 10 having 2,6-anhydro-2-thio structures, respectively, which were prepared from the common intermediate 6 in stereocontrolled fashion.

本文言語English
ページ(範囲)4139-4142
ページ数4
ジャーナルTetrahedron Letters
32
33
DOI
出版ステータスPublished - 1991 8月 12

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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