Dearomative Oxidative Rearrangement of [3]Cyclo-1,8-carbazolylene

Masamichi Yasui, Hiroyoshi Ohtsu, Masaki Kawano, Kengo Hanaya, Takeshi Sugai, Shuhei Higashibayashi

研究成果: Article査読

抄録

[3]Cyclo-1,8-carbazolylene was found to undergo oxidative rearrangement by oxidation with 2,3-dichloro-5,6-dicyano-pbenzoquinone, giving a 9a-substituted carbazol-1-one derivative. This is the first example of a dearomative oxidative rearrangement of a carbazole or aniline derivative. The geometrical and electronic structures were elucidated by X-ray analysis, UV-vis absorption spectroscopy, and DFT calculations.

本文言語English
ページ(範囲)1357-1359
ページ数3
ジャーナルChemistry Letters
47
11
DOI
出版ステータスPublished - 2018

ASJC Scopus subject areas

  • 化学 (全般)

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