Design of Efficient Chiral Bifunctional Phase-Transfer Catalysts Possessing an Amino Functionality for Asymmetric Aminations

Suva Paria, Qi Kai Kang, Miho Hatanaka, Keiji Maruoka

研究成果: Article査読

9 被引用数 (Scopus)

抄録

An efficient, chiral bifunctional phase-transfer catalyst with an intramolecular amino functionality has been designed and successfully applied to highly enantioselective amination of 3-aryloxindoles and 3-arylbenzofuran-2(3H)-ones with bis(adamantyl) azodicarboxylate. Optically active amination products were generally obtained in high yield with high enantioselectivity. The origin of stereoselectivity was explained by means of the DFT calculations. ©

本文言語English
ページ(範囲)78-82
ページ数5
ジャーナルACS Catalysis
9
1
DOI
出版ステータスPublished - 2019 1 4
外部発表はい

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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