抄録
Deuterium-labeling experiments were performed for the Fe(PMe 3) 4-catalyzed C-H/olefin coupling using a deuterium-labeled aromatic ketone with various alkenes. While the reactions with a variety of alkenes provided the linear alkylation products formed via 1,2-insertion of alkene into an Fe-H bond, the reversible 2,1-insertion proceeded during the reaction highly depends on the choice of the alkene. No H/D scrambling resulting from 2,1-insertion/β-elimination was detected for the reactions with a vinylsilane and N -vinylcarbazole, but the reactions with styrenes are considered to involve rapid 2,1-insertion/ β-elimination processes to cause significant levels of H/D scrambling.
本文言語 | English |
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ページ(範囲) | 3383-3389 |
ページ数 | 7 |
ジャーナル | Synthesis (Germany) |
巻 | 53 |
号 | 18 |
DOI | |
出版ステータス | Published - 2021 9月 16 |
ASJC Scopus subject areas
- 触媒
- 有機化学