Development of dual functional methodology for seawater desalination and salt manufacture by carbon dioxide hydrate formation

Akari Gibo, Seiya Nakao, Sayaka Shiraishi, Satoshi Takeya, Shigeo Tomura, Ryo Ohmura, Keita Yasuda

研究成果: Article査読

抄録

Clathrate-hydrate-based seawater desalination is a novel technology that is performed by reaction between seawater and guest compounds to obtain fresh water. This study proposed a dual functional methodology for seawater desalination and salt manufacture by using carbon dioxide clathrate hydrate. In this methodology, the clathrate hydrate formation continues until the concentration of electrolytes in unreacted brine reaches the saturated solubility for the salt precipitation. The visual observation of the clathrate hydrate formation and the salt precipitation coupled with the analysis utilizing the powder X-ray diffraction (PXRD) technique was implemented to demonstrate the methodology. The carbon dioxide clathrate hydrate formation was first performed with sodium chloride aqueous solution. The carbon dioxide clathrate hydrate crystals floated on high salinity water. This experiment was followed by the occurrence of the sodium chloride dihydrate precipitation upon the carbon dioxide clathrate hydrate formation. The formed compounds, carbon dioxide clathrate hydrate and sodium chloride dihydrate, were identified by PXRD analysis. The mass fraction of the compounds was also determined by PXRD.

本文言語English
論文番号115937
ジャーナルDesalination
539
DOI
出版ステータスPublished - 2022 10月 1

ASJC Scopus subject areas

  • 化学 (全般)
  • 化学工学(全般)
  • 材料科学(全般)
  • 水の科学と技術
  • 機械工学

フィンガープリント

「Development of dual functional methodology for seawater desalination and salt manufacture by carbon dioxide hydrate formation」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル