Development of light-modulated XAFS spectroscopy

Kaoru Okamoto, Kenji Kohdate, Kensuke Nagai, Jun Miyawaki, Hiroshi Kondoh, Toshihiko Yokoyama, Akihiro Nojima, Toshiaki Ohta

研究成果: Article査読

7 被引用数 (Scopus)

抄録

The light-modulation method was applied to XAFS spectroscopy as a useful tool for electronic and structural studies of light-excited states. The visible light for electronic excitation was modulated by an optical chopper and the concomitant change in the X-ray absorbance was extracted by a lock-in amplifier. It is essential to reduce any noise arising from several sources, especially those generated by the X-ray monochromator. Fe and Co K-edge XANES and EXAFS spectra were measured using the present approach for spin transition compounds. The light-modulated XAFS method is found to be applicable to systems with an excited-state ratio of less than several percent. Detailed discussion is also given concerning quantitative measurements, including the signal amplitude and phase shift information.

本文言語English
ページ(範囲)242-247
ページ数6
ジャーナルJournal of Synchrotron Radiation
10
3
DOI
出版ステータスPublished - 2003 5 1
外部発表はい

ASJC Scopus subject areas

  • 放射線
  • 核物理学および高エネルギー物理学
  • 器械工学

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