Polythioester shows some unique characteristics such as high melting point and poor solubility against various organic solvents. This report covers the synthesis of polythioester from α, ω) -alkanedithiol and diethyl α, ω) -alkanedioate using the lipase-catalyzed reaction. The T m and Tc for all of the obtained polythioester were higher than those of the corresponding polyoxoester analogues. The obtained polythioester showed an odd-even effect.
|出版物ステータス||Published - 2005 12 1|
|イベント||54th SPSJ Symposium on Macromolecules - Yamagata, Japan|
継続期間: 2005 9 20 → 2005 9 22
|Other||54th SPSJ Symposium on Macromolecules|
|期間||05/9/20 → 05/9/22|
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