Direct observation of conformers caused by the difference in ligand orientation in low spin iron(III) porphyrin complex

Takahisa Ikeue, Tatsuya Yamaguchi, Yoshiki Ohgo, Mikio Nakamura

研究成果: Article査読

6 被引用数 (Scopus)

抄録

EPR spectrum of low spin bis(dimethylaminopyridine)(3,8, 13,18-tetramesityl-2,7,12,17-tetramethylporphyrinato)iron(III) perchlorate taken in frozen CH2Cl2 solution at 4.2 K showed both large gmax and rhombic type signals. The result has been explained in terms of the presence of two conformers where the dihedral angles between two ligands are different.

本文言語English
ページ(範囲)342-343
ページ数2
ジャーナルChemistry Letters
4
DOI
出版ステータスPublished - 2000 1 1

ASJC Scopus subject areas

  • 化学 (全般)

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