Direct synthesis of organochlorosilanes by the reaction of metallic silicon with hydrogen chloride and alkene/alkyne

Masaki Okamoto; Satoshi Onodera; Yuji Yamamoto; Eiichi Suzuki; Yoshio Ono

doi:10.1039/a800121i

Direct synthesis of organochlorosilanes by the reaction of metallic silicon with hydrogen chloride and alkene/alkyne

Masaki Okamoto, Satoshi Onodera, Yuji Yamamoto, Eiichi Suzuki, Yoshio Ono

研究成果: Article › 査読

8 被引用数 (Scopus)

抄録

Organosilicon compounds were directly synthesized from metallic silicon, alkene/alkyne and HCl, EtHSiCl₂ being obtained with 47% selectivity from Si, C₂H₄ and HCl at 513 K, and CH₂=CHSiHCl₂ and EtHSiCl₂ with 39 and 23% selectivity, respectively, when C₂H₂ was used in place of C₂H₄.

本文言語	English
ページ（範囲）	1275-1276
ページ数	2
ジャーナル	Chemical Communications
号	12
DOI	https://doi.org/10.1039/a800121i
出版ステータス	Published - 1998 6月 21
外部発表	はい

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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title = "Direct synthesis of organochlorosilanes by the reaction of metallic silicon with hydrogen chloride and alkene/alkyne",

abstract = "Organosilicon compounds were directly synthesized from metallic silicon, alkene/alkyne and HCl, EtHSiCl2 being obtained with 47% selectivity from Si, C2H4 and HCl at 513 K, and CH2=CHSiHCl2 and EtHSiCl2 with 39 and 23% selectivity, respectively, when C2H2 was used in place of C2H4.",

author = "Masaki Okamoto and Satoshi Onodera and Yuji Yamamoto and Eiichi Suzuki and Yoshio Ono",

year = "1998",

month = jun,

day = "21",

doi = "10.1039/a800121i",

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T1 - Direct synthesis of organochlorosilanes by the reaction of metallic silicon with hydrogen chloride and alkene/alkyne

AU - Okamoto, Masaki

AU - Onodera, Satoshi

AU - Yamamoto, Yuji

AU - Suzuki, Eiichi

AU - Ono, Yoshio

PY - 1998/6/21

Y1 - 1998/6/21

N2 - Organosilicon compounds were directly synthesized from metallic silicon, alkene/alkyne and HCl, EtHSiCl2 being obtained with 47% selectivity from Si, C2H4 and HCl at 513 K, and CH2=CHSiHCl2 and EtHSiCl2 with 39 and 23% selectivity, respectively, when C2H2 was used in place of C2H4.

AB - Organosilicon compounds were directly synthesized from metallic silicon, alkene/alkyne and HCl, EtHSiCl2 being obtained with 47% selectivity from Si, C2H4 and HCl at 513 K, and CH2=CHSiHCl2 and EtHSiCl2 with 39 and 23% selectivity, respectively, when C2H2 was used in place of C2H4.

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DO - 10.1039/a800121i

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Direct synthesis of organochlorosilanes by the reaction of metallic silicon with hydrogen chloride and alkene/alkyne

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