Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts

Masaki Okamoto, Takuya Asano, Eiichi Suzuki

研究成果: Article査読

6 被引用数 (Scopus)

抄録

In the direct synthesis of phenylchlorogermanes, copper(I) chloride was the best catalyst among the metal chlorides tested, the products being diphenyldichlorogermane and phenyltrichlorogermane. The reaction mainly gave diphenyldichlorogermane; however at the beginning of the reaction, phenyltrichlorogermane was afforded by the reaction of chlorobenzene and dichlorogermylene formed from metallic germanium and chloride ion in the catalyst.

本文言語English
ページ(範囲)33-36
ページ数4
ジャーナルCatalysis Letters
78
1-4
DOI
出版ステータスPublished - 2002 3
外部発表はい

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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