Directing effect of functional groups in ruthenium-catalyzed addition of substituted acetophonones to an olefin

Motohiro Sonoda, Fumitoshi Kakiuchi, Naoto Chatani, Shinji Murai

研究成果: Article

58 引用 (Scopus)

抜粋

Ruthenium-catalyzed addition of 3′-methyl-, 3′-trifluoromethyl-, and 3′-N,N-dimethylaminoacetophenones to an olefin proceeds site selectively at 6′ CH bonds to give the 1:1 CH/olefin addition products in high yields. In contrast, the addition of 3′-methoxyacetophenone takes place preferentially at the CH bond at the more congested 2′ position.

元の言語English
ページ(範囲)151-152
ページ数2
ジャーナルJournal of Organometallic Chemistry
504
発行部数1-2
DOI
出版物ステータスPublished - 1995 11 29
外部発表Yes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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