Dynamic kinetic resolution with enantioselective borohydride reduction catalyzed by optically active β-ketoiminato cobalt(II) complexes: Highly diastereo- and enantioselective preparation of optically active anti-aldol compounds

Yuhki Ohtsuka, Daichi Miyazaki, Taketo Ikeno, Tohru Yamada

研究成果: Article査読

20 被引用数 (Scopus)

抄録

Optically active anti-2-alkyl-3-hydroxy esters were stereo-selectively obtained from the corresponding 2-alkyl-3-keto esters using enantioselective borohydride reduction along with dynamic kinetic resolution in the presence of optically active β-ketoiminato cobalt complex catalysts. The reduction system provided an alternative preparation for anti-aldol compounds with high diastereo- and enantioselectivities.

本文言語English
ページ(範囲)24-25
ページ数2
ジャーナルChemistry Letters
1
DOI
出版ステータスPublished - 2002 1月 5

ASJC Scopus subject areas

  • 化学 (全般)

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「Dynamic kinetic resolution with enantioselective borohydride reduction catalyzed by optically active β-ketoiminato cobalt(II) complexes: Highly diastereo- and enantioselective preparation of optically active anti-aldol compounds」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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