Effects of a nonplanar porphyrin rings on the spin-spin interactions in low-spin ferric porphyrin radical cations

Takahisa Ikeue, Yoshiki Ohgo, Mikio Nakamura

研究成果: Article

9 引用 (Scopus)

抜粋

Low-spin ferric porphyrin radical cations formed by the oxidation of chloro(meso-tetraalkylporphyrinato)iron(III) followed by the addition of bulky 2-methylimidazole show antiferromagnetic coupling, which is interpreted in terms of the interaction between porphyrin a2u and iron dxy orbitals caused by the S4 ruffling of the porphyrin core.

元の言語English
ページ(範囲)220-221
ページ数2
ジャーナルChemical Communications
発行部数2
DOI
出版物ステータスPublished - 2003

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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