Effects of a nonplanar porphyrin rings on the spin-spin interactions in low-spin ferric porphyrin radical cations

Takahisa Ikeue, Yoshiki Ohgo, Mikio Nakamura

研究成果: Article

9 引用 (Scopus)

抄録

Low-spin ferric porphyrin radical cations formed by the oxidation of chloro(meso-tetraalkylporphyrinato)iron(III) followed by the addition of bulky 2-methylimidazole show antiferromagnetic coupling, which is interpreted in terms of the interaction between porphyrin a2u and iron dxy orbitals caused by the S4 ruffling of the porphyrin core.

元の言語English
ページ(範囲)220-221
ページ数2
ジャーナルChemical Communications
9
発行部数2
DOI
出版物ステータスPublished - 2003

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Porphyrins
Cations
Positive ions
Iron
Oxidation

ASJC Scopus subject areas

  • Chemistry(all)

これを引用

Effects of a nonplanar porphyrin rings on the spin-spin interactions in low-spin ferric porphyrin radical cations. / Ikeue, Takahisa; Ohgo, Yoshiki; Nakamura, Mikio.

:: Chemical Communications, 巻 9, 番号 2, 2003, p. 220-221.

研究成果: Article

Ikeue, Takahisa ; Ohgo, Yoshiki ; Nakamura, Mikio. / Effects of a nonplanar porphyrin rings on the spin-spin interactions in low-spin ferric porphyrin radical cations. :: Chemical Communications. 2003 ; 巻 9, 番号 2. pp. 220-221.
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