Electro-conversion of cumene into acetophenone using boron-doped diamond electrodes

Mana Kitano, Tsuyoshi Saitoh, Shigeru Nishiyama, Yasuaki Einaga, Takashi Yamamoto

研究成果: Article査読

抄録

A straightforward electro-conversion of cumene into acetophenone has been reported using boron-doped diamond (BDD) electrodes. This particular conversion is driven by the addition reaction of a cathodically generated hydroperoxide anion to an anodically generated cumyl cation, where the BDD's wide potential window enables the direct anodic oxidation of cumene into the cumyl cation. Since electricity is directly employed as the oxidizing and reducing reagents, the present protocol is easy to use, suitable for scale-up, and inherently safe.

本文言語English
ページ(範囲)1154-1158
ページ数5
ジャーナルBeilstein Journal of Organic Chemistry
18
DOI
出版ステータスPublished - 2022

ASJC Scopus subject areas

  • 有機化学

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