抜粋
The electrochemical behaviors of divalent iron species were investigated in a room-temperature molten salt (RTMS) consisting of 1-n-butyl-1- methylpyrrolidinium cation (BMP+) and bis(trifluoromethylsulfonyl) imide (TFSI-) anion. The TFSI--salt of Fe(II) was soluble in BMPTFSI at room temperature. The cyclic voltammetric data for the Fe(III)/ Fe(II) processes at 1.1 V vs. Ag/Ag(I) showed quasi-reversible kinetics on a platinum electrode. The diffusion coefficient of Fe(II) determined by chronoamperometric techniques was 9.7 × 10-8 cm2 s-1 at 25°C. After cathodic reduction of Fe(II) at - 2.0 V, furthermore, metallic Fe was electrodeposited on a copper substrate.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 564-566 |
| ページ数 | 3 |
| ジャーナル | Electrochemistry |
| 巻 | 73 |
| 発行部数 | 8 |
| DOI | |
| 出版物ステータス | Published - 2005 8 |
ASJC Scopus subject areas
- Electrochemistry
フィンガープリント Electrochemical behavior of iron(II) species in a hydrophobic room-temperature molten salt' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。
これを引用
Yamagata, M., Tachikawa, N., Katayama, Y., & Miura, T. (2005). Electrochemical behavior of iron(II) species in a hydrophobic room-temperature molten salt. Electrochemistry, 73(8), 564-566. https://doi.org/10.5796/electrochemistry.73.564