Electrochemically Generated ArS(ArSSAr)+B(C6F 5)4- as an Activator of Thioglycosides for Glycosylation

Kodai Saito, Yoshihiro Saigusa, Toshiki Nokami, Jun Ichi Yoshida

研究成果: Article

16 引用 (Scopus)

抄録

Electrochemically generated ArS(ArSSAr)+ was found to be an effective activator for glycosylation of thioglycosides. Efficiency of the reaction strongly depends on the nature of the counter anion, and B(C 6F5)4 - was the most effective among those examined. The method was applicable to various glyocosyl donors including thiogalactosides and thiomannosides and various acceptors including those having secondary hydroxy groups.

元の言語English
ページ(範囲)678-679
ページ数2
ジャーナルChemistry Letters
40
発行部数7
DOI
出版物ステータスPublished - 2011
外部発表Yes

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Thioglycosides
Thiogalactosides
Glycosylation
Anions

ASJC Scopus subject areas

  • Chemistry(all)

これを引用

Electrochemically Generated ArS(ArSSAr)+B(C6F 5)4- as an Activator of Thioglycosides for Glycosylation. / Saito, Kodai; Saigusa, Yoshihiro; Nokami, Toshiki; Yoshida, Jun Ichi.

:: Chemistry Letters, 巻 40, 番号 7, 2011, p. 678-679.

研究成果: Article

Saito, Kodai ; Saigusa, Yoshihiro ; Nokami, Toshiki ; Yoshida, Jun Ichi. / Electrochemically Generated ArS(ArSSAr)+B(C6F 5)4- as an Activator of Thioglycosides for Glycosylation. :: Chemistry Letters. 2011 ; 巻 40, 番号 7. pp. 678-679.
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