Electrochemically Generated ArS(ArSSAr)+B(C6F 5)4- as an Activator of Thioglycosides for Glycosylation

Kodai Saito, Yoshihiro Saigusa, Toshiki Nokami, Jun Ichi Yoshida

研究成果: Article

16 引用 (Scopus)

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Electrochemically generated ArS(ArSSAr)+ was found to be an effective activator for glycosylation of thioglycosides. Efficiency of the reaction strongly depends on the nature of the counter anion, and B(C 6F5)4- was the most effective among those examined. The method was applicable to various glyocosyl donors including thiogalactosides and thiomannosides and various acceptors including those having secondary hydroxy groups.

元の言語English
ページ(範囲)678-679
ページ数2
ジャーナルChemistry Letters
40
発行部数7
DOI
出版物ステータスPublished - 2011 6 24
外部発表Yes

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ASJC Scopus subject areas

  • Chemistry(all)

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