Electrochemically Generated ArS(ArSSAr)+B(C6F 5)4- as an Activator of Thioglycosides for Glycosylation

Kodai Saito; Yoshihiro Saigusa; Toshiki Nokami; Jun Ichi Yoshida

doi:10.1246/cl.2011.678

Electrochemically Generated ArS(ArSSAr)⁺B(C₆F ₅)_4- as an Activator of Thioglycosides for Glycosylation

Kodai Saito, Yoshihiro Saigusa, Toshiki Nokami, Jun Ichi Yoshida

研究成果: Article › 査読

20 被引用数 (Scopus)

抄録

Electrochemically generated ArS(ArSSAr)⁺ was found to be an effective activator for glycosylation of thioglycosides. Efficiency of the reaction strongly depends on the nature of the counter anion, and B(C ₆F₅)₄^- was the most effective among those examined. The method was applicable to various glyocosyl donors including thiogalactosides and thiomannosides and various acceptors including those having secondary hydroxy groups.

本文言語	English
ページ（範囲）	678-679
ページ数	2
ジャーナル	Chemistry Letters
巻	40
号	7
DOI	https://doi.org/10.1246/cl.2011.678
出版ステータス	Published - 2011
外部発表	はい

ASJC Scopus subject areas

化学 (全般)

文献へのアクセス

10.1246/cl.2011.678

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引用スタイル

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