Electrodeposition of cobalt from an imide-type room-temperature ionic liquid

Yasushi Katayama, Ryuta Fukui, Takashi Miura

研究成果: Article

73 引用 (Scopus)

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The electrodeposition of cobalt was investigated in an ionic liquid, 1- n -butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide. The overpotential for the electrodeposition of Co was reduced remarkably by elevating the temperature up to 200°C, probably due to the change in the coordination environment of Co species. The addition of acetone led to the decrease in the overpotential, indicating the selective coordination of Co cation with acetone enhanced the charge transfer rate. It has been suggested that the charge transfer and crystal growth in the ionic liquid are affected by the coordination environment of the dissolved metal species and the structure of electric double layer.

元の言語English
ページ(範囲)D534-D537
ジャーナルJournal of the Electrochemical Society
154
発行部数10
DOI
出版物ステータスPublished - 2007 8 31

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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