Electronic and geometric structures of aluminum-boron negative cluster ions (AlnB- m)

Atsushi Nakajima, Takashi Kishi, Tsuneyoshi Sugioka, Koji Kaya

研究成果: Article査読

60 被引用数 (Scopus)

抄録

Aluminum-boron negative cluster ions (AlnB- m, n=5-30, m=1-3) were generated by two independent laser-vaporization sources. The mass distribution of AlnB- 2 exhibits one peak at n=12 and one step between n=22 and 23 as magic numbers, whereas that of AlnB- 2 exhibits only one step between n=21 and 22. The loss of the magic number of Al11B- 2 can be explained by the geometric structures: Al12B- 1 is stabilized by both an electronic shell closing of the 2p shell and a close-packing structure of icosahedron. In contrast, Al11B- 2 can satisfy the electronic shell closing by cannot take the stable geometric structure because the diameters of Al and B atoms differ largely. The structure of Al12B- 1 can be an icosahedron with a B atom located at the center.

本文言語English
ページ(範囲)239-244
ページ数6
ジャーナルChemical Physics Letters
187
3
DOI
出版ステータスPublished - 1991 12 6

ASJC Scopus subject areas

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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