Electronic properties of organometallic metal-benzene complexes [Mn(benzene)m (M = Sc-Cu)]

Tsuyoshi Kurikawa, Hiroaki Takeda, Masaaki Hirano, Ken Judai, Tadashi Arita, Satoshi Nagao, Atsushi Nakajima, Koji Kaya

研究成果: Article査読

224 被引用数 (Scopus)

抄録

Neutral metal-benzene complexes, Mn(benzene)m (M = Sc to Cu), are produced for all of the 3d transition metals in the gas phase by using the laser vaporization method. These species are characterized by mass spectrometry, photoionization spectroscopy, and chemical probe experiments. Depending on the metal, there are two types of structures for Mn(benzene)m: multiple-decker sandwich structures and metal clusters fully covered with benzene molecules (rice-ball structures). The former sandwich structure is characteristic of the complexes for early transition metals (Sc-V), whereas the latter is formed for late transition metals (Fe-Ni). Electronic structures of M1(benzene)x (x = 1, 2) complexes are investigated through systematic measurements of ionization energies (Ei's).

本文言語English
ページ(範囲)1430-1438
ページ数9
ジャーナルOrganometallics
18
8
DOI
出版ステータスPublished - 1999 4 12

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 有機化学
  • 無機化学

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