Electronic structures of exohedral lanthanide-C60 clusters

Jun Ichi Suzumura, Natsuki Hosoya, Satoshi Nagao, Masaaki Mitsui, Atsushi Nakajima

研究成果: Article査読

6 被引用数 (Scopus)

抄録

The electronic structures of several gas phase exohedral lanthanide (Ln)-C60, LnnC60 with n=1-4, clusters were discussed. it was shown that most of the Ln atoms preferably take +3 oxidation states, while Eu atoms alone assume +2 oxidation states, and that C60 accepts up to twelve donated electrons in LnnC60. The photoionization examination of the oxygen atom mixing into the Ln nC60 clusters showed that each oxygen atom reduces two electrons from C60. It was suggested that the number of accepted electrons in C60 can be varied by a suitable choice of the number of Ln atoms and O atoms.

本文言語English
ページ(範囲)2649-2654
ページ数6
ジャーナルJournal of Chemical Physics
121
6
DOI
出版ステータスPublished - 2004 8月 8

ASJC Scopus subject areas

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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