Emergence of chiral environments by effect of flows: The case of an ionic oligomer and Congo red dye

Kunihiko Okano, Oriol Arteaga, Josep M. Ribo, Takashi Yamashita

研究成果: Article

22 引用 (Scopus)

抜粋

Mechanical chiral induction: In aqueous solutions of a cationic oligomer that forms interchain cross-linking through non-covalent interactions, chiral regions can be obtained reversibly by stirring flows. The chiral induction upon an achiral molecule (Congo Red dye) was demonstrated by Mueller matrix spectroscopy analysis of the optical polarization properties. Shown here is the true CD image of a stirred solution, clockwise (top) and counterclockwise (bottom), of compound 1.

元の言語English
ページ(範囲)9288-9292
ページ数5
ジャーナルChemistry - A European Journal
17
発行部数34
DOI
出版物ステータスPublished - 2011 8 16

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ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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