Enantioselective Reduction of Ketones with Sodium Borohydride, Catalyzed by Optically Active (β‐Oxoaldiminato)cobalt(II) Complexes

Takushi Nagata; Kiyotaka Yorozu; Tohru Yamada; Teruaki Mukaiyama

doi:10.1002/anie.199521451

Enantioselective Reduction of Ketones with Sodium Borohydride, Catalyzed by Optically Active (β‐Oxoaldiminato)cobalt(II) Complexes

Takushi Nagata, Kiyotaka Yorozu, Tohru Yamada, Teruaki Mukaiyama

研究成果: Article › 査読

155 被引用数 (Scopus)

抄録

Asymmetric reduction of prochiral ketones with sodium borohydride proceeds in the presence of catalytic amounts of optically active β‐oxoaldiminatocobalt(II) complexes 1 to the corresponding optically active secondary alcohols in high chemical yields with high enantioselectivities (68–94% ee). (Figure Presented.)

本文言語	English
ページ（範囲）	2145-2147
ページ数	3
ジャーナル	Angewandte Chemie International Edition in English
巻	34
号	19
DOI	https://doi.org/10.1002/anie.199521451
出版ステータス	Published - 1995 10月 16
外部発表	はい

ASJC Scopus subject areas

触媒
化学 (全般)

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10.1002/anie.199521451

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AU - Mukaiyama, Teruaki

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