Enantioselective transfer hydrogenation of difluoromethyl ketimines using benzothiazoline as a hydrogen donor in combination with a chiral phosphoric acid

Tsubasa Sakamoto, Kosaku Horiguchi, Kodai Saito, Keiji Mori, Takahiko Akiyama

研究成果: Article査読

13 被引用数 (Scopus)

抄録

Hold the benzothiazoline: Highly enantioselective transfer hydrogenation of difluoromethyl ketimines with benzothiazolines catalyzed by a chiral phosphoric acid furnishes α-difluoromethylated amines in good yields and with excellent enantioselectivity, irrespective of the stereochemistry of the starting materials. PMP=p-methoxyphenyl.

本文言語English
ページ(範囲)943-946
ページ数4
ジャーナルAsian Journal of Organic Chemistry
2
11
DOI
出版ステータスPublished - 2013 11
外部発表はい

ASJC Scopus subject areas

  • Organic Chemistry

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