In the title mononuclear oxovanadium(IV) complex, [VO(C21H24N2O4)], the methyl group of the central diamine moiety in the Schiff base ligand is directed opposite to the oxo ligand. This endo isomer elutes more slowly than the exo isomer when subjected to high-performance liquid reversed-phase chromatography using CH3CN-H2O (1:1 v/v) as the eluent. Crystals of both the endo and exo isomers decompose at 473 K, with no solid-state isomerization from endo to exo or vice versa.
|ジャーナル||Acta Crystallographica Section C: Crystal Structure Communications|
|出版ステータス||Published - 1999 11 15|
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)