endo-{6,6′-Diethoxy-2,2′-[(R)-propane-1,2- diylbis(nitrilomethylidene)]diphenolato-O,N,N′,O′}oxovanadium(IV)

Gakuse Hoshina, Masanobu Tsuchimoto, Shigeru Ohba

研究成果: Article査読

13 被引用数 (Scopus)

抄録

In the title mononuclear oxovanadium(IV) complex, [VO(C21H24N2O4)], the methyl group of the central diamine moiety in the Schiff base ligand is directed opposite to the oxo ligand. This endo isomer elutes more slowly than the exo isomer when subjected to high-performance liquid reversed-phase chromatography using CH3CN-H2O (1:1 v/v) as the eluent. Crystals of both the endo and exo isomers decompose at 473 K, with no solid-state isomerization from endo to exo or vice versa.

本文言語English
ページ(範囲)1812-1813
ページ数2
ジャーナルActa Crystallographica Section C: Crystal Structure Communications
55
11
DOI
出版ステータスPublished - 1999 11 15

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

フィンガープリント 「endo-{6,6′-Diethoxy-2,2′-[(R)-propane-1,2- diylbis(nitrilomethylidene)]diphenolato-O,N,N′,O′}oxovanadium(IV)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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