抄録
Kinetic resolution of racemic 1-cyano-1-methylalkyl and alkenyl acetates has been achieved on incubation with Pichia miso IAM 4682, which hydolyzed selectively the (R)-enantiomer, leaving behind the (S)-enantiomer intact. The chiral 1-cyano-1-methyl-5-hexenyl acetate thus obtained was converted to (S)-(-)-frontalin via unsaturated diol.
本文言語 | English |
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ページ(範囲) | 5469-5476 |
ページ数 | 8 |
ジャーナル | Tetrahedron |
巻 | 45 |
号 | 17 |
DOI | |
出版ステータス | Published - 1989 |
ASJC Scopus subject areas
- 生化学
- 創薬
- 有機化学