Enzymatic preparation of malate-based polycarboxylates having higher molecular weights by copolymerization with lactone

Shuichi Matsumura; Hideki Beppu; Kazunobu Toshima

doi:10.1246/cl.1999.249

Enzymatic preparation of malate-based polycarboxylates having higher molecular weights by copolymerization with lactone

Shuichi Matsumura, Hideki Beppu, Kazunobu Toshima

応用化学科

研究成果: Article › 査読

21 被引用数 (Scopus)

抄録

A strategy for increasing the molecular weight of malate-based polycarboxylates by the enzymatic polymerization of benzyl β-malolactonate (BML) with organic additives was studied. The lipase-catalyzed ring-opening polymerization of BML was significantly promoted by the addition of a small amount of β-propiolactone (PL) to yield polycarboxylates having an M̄_w of 32000 without a significant decrease in the inherent carboxy content.

本文言語	English
ページ（範囲）	249-250
ページ数	2
ジャーナル	Chemistry Letters
号	3
DOI	https://doi.org/10.1246/cl.1999.249
出版ステータス	Published - 1999 1月 1

ASJC Scopus subject areas

化学 (全般)

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10.1246/cl.1999.249

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Enzymatic preparation of malate-based polycarboxylates having higher molecular weights by copolymerization with lactone

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