Enzyme-catalyzed ring-opening polymerization of 1,3-dioxan-2-one to poly(trimethylene carbonate)

Shuichi Matsumura, Keisuke Tsukada, Kazunobu Toshima

研究成果: Article査読

128 被引用数 (Scopus)

抄録

The preparation of poly(trimethylene carbonate) [P(TMC)] by the enzymatic ring-opening polymerization of the six member, 1,3-dioxan-2-one (TMC) is studied with respect to the reaction conditions and origin of the enzyme. It was found that cyclic carbonate TMC was readily polymerized in the presence of lipase at the corresponding P(TMC). No elimination of carbon dioxide by the enzymatic preparation of TMC was detected.

本文言語English
ページ(範囲)3122-3124
ページ数3
ジャーナルMacromolecules
30
10
DOI
出版ステータスPublished - 1997 1月 1

ASJC Scopus subject areas

  • 有機化学
  • ポリマーおよびプラスチック
  • 無機化学
  • 材料化学

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