Enzyme-catalyzed ring-opening polymerization of 1,3-dioxan-2-one to poly(trimethylene carbonate)

Shuichi Matsumura, Keisuke Tsukada, Kazunobu Toshima

研究成果: Article

124 引用 (Scopus)

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The preparation of poly(trimethylene carbonate) [P(TMC)] by the enzymatic ring-opening polymerization of the six member, 1,3-dioxan-2-one (TMC) is studied with respect to the reaction conditions and origin of the enzyme. It was found that cyclic carbonate TMC was readily polymerized in the presence of lipase at the corresponding P(TMC). No elimination of carbon dioxide by the enzymatic preparation of TMC was detected.

元の言語English
ページ(範囲)3122-3124
ページ数3
ジャーナルMacromolecules
30
発行部数10
DOI
出版物ステータスPublished - 1997 1 1

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ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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