Ethylene oligomerization catalyzed with dichlorobis-(β-diketonato)zirconium/organoaluminium chloride systems

Kunihiro Oouchi, Makoto Mitani, Michiya Hayakawa, Tohru Yamada, Teruaki Mukaiyama

研究成果: Article

44 引用 (Scopus)

抄録

The combination of a dichlorobis(β-diketonato)zirconium compound 1 and dimethylaluminium chloride was found to be an active catalyst for the oligomerization of ethylene to produce linear C4-C22 α-olefins. The catalytic activity and the product distribution of the resulting oligomers was influenced by the structure of the β-diketonato ligands, which affect the electron density at the zirconium center.

元の言語English
ページ(範囲)1545-1551
ページ数7
ジャーナルMacromolecular Chemistry and Physics
197
発行部数4
出版物ステータスPublished - 1996 4
外部発表Yes

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Zirconium compounds
zirconium compounds
Oligomerization
Alkenes
oligomers
Oligomers
Zirconium
alkenes
Olefins
Carrier concentration
catalytic activity
Catalyst activity
Ethylene
ethylene
chlorides
Ligands
catalysts
ligands
Catalysts
products

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Polymers and Plastics

これを引用

Ethylene oligomerization catalyzed with dichlorobis-(β-diketonato)zirconium/organoaluminium chloride systems. / Oouchi, Kunihiro; Mitani, Makoto; Hayakawa, Michiya; Yamada, Tohru; Mukaiyama, Teruaki.

:: Macromolecular Chemistry and Physics, 巻 197, 番号 4, 04.1996, p. 1545-1551.

研究成果: Article

Oouchi, Kunihiro ; Mitani, Makoto ; Hayakawa, Michiya ; Yamada, Tohru ; Mukaiyama, Teruaki. / Ethylene oligomerization catalyzed with dichlorobis-(β-diketonato)zirconium/organoaluminium chloride systems. :: Macromolecular Chemistry and Physics. 1996 ; 巻 197, 番号 4. pp. 1545-1551.
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