Ethylene oligomerization catalyzed with dichlorobis-(β-diketonato)zirconium/organoaluminium chloride systems

Kunihiro Oouchi; Makoto Mitani; Michiya Hayakawa; Tohru Yamada; Teruaki Mukaiyama

doi:10.1002/macp.1996.021970430

Ethylene oligomerization catalyzed with dichlorobis-(β-diketonato)zirconium/organoaluminium chloride systems

Kunihiro Oouchi, Makoto Mitani, Michiya Hayakawa, Tohru Yamada, Teruaki Mukaiyama

研究成果: Article › 査読

47 被引用数 (Scopus)

抄録

The combination of a dichlorobis(β-diketonato)zirconium compound 1 and dimethylaluminium chloride was found to be an active catalyst for the oligomerization of ethylene to produce linear C₄-C₂₂ α-olefins. The catalytic activity and the product distribution of the resulting oligomers was influenced by the structure of the β-diketonato ligands, which affect the electron density at the zirconium center.

本文言語	English
ページ（範囲）	1545-1551
ページ数	7
ジャーナル	Macromolecular Chemistry and Physics
巻	197
号	4
DOI	https://doi.org/10.1002/macp.1996.021970430
出版ステータス	Published - 1996 4月
外部発表	はい

ASJC Scopus subject areas

凝縮系物理学
物理化学および理論化学
ポリマーおよびプラスチック
有機化学
材料化学

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10.1002/macp.1996.021970430

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abstract = "The combination of a dichlorobis(β-diketonato)zirconium compound 1 and dimethylaluminium chloride was found to be an active catalyst for the oligomerization of ethylene to produce linear C4-C22 α-olefins. The catalytic activity and the product distribution of the resulting oligomers was influenced by the structure of the β-diketonato ligands, which affect the electron density at the zirconium center.",

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AU - Yamada, Tohru

AU - Mukaiyama, Teruaki

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Ethylene oligomerization catalyzed with dichlorobis-(β-diketonato)zirconium/organoaluminium chloride systems

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