Evaporation and condensation at a liquid surface. II. Methanol

Mitsuhiro Matsumoto, Kenji Yasuoka, Yosuke Kataoka

研究成果: Article査読

70 被引用数 (Scopus)

抄録

The rates of evaporation and condensation of methanol under the vapor-liquid equilibrium condition at the temperature of 300 and 350 K are investigated with a molecular dynamics computer simulation. Compared with the argon system (reported in part I), the ratio of self-reflection is similar (∼10%), but the ratio of molecule exchange is several times larger than the argon, which suggests that the conventional assumption of condensation as a unimolecular process completely fails for associating fluids. The resulting total condensation coefficient is 20%-25%, and has a quantitative agreement with a recent experiment. The temperature dependence of the evaporation-condensation behavior is not significant.

本文言語English
ページ(範囲)7912-7917
ページ数6
ジャーナルThe Journal of Chemical Physics
101
9
DOI
出版ステータスPublished - 1994
外部発表はい

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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