Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system: [FeIII(qnal) 2][Pd(dmit)2]5·acetone

Kazuyuki Takahashi, Heng Bo Cui, Yoshinori Okano, Hayao Kobayashi, Hatsumi Mori, Hiroyuki Tajima, Yasuaki Einaga, Osamu Sato

研究成果: Article査読

135 被引用数 (Scopus)

抄録

A novel spin-crossover molecular conductor, [Fe(qnal)2][Pd(dmit)2]5·acetone, was prepared and characterized. The crystal structural analyses of both the low- and high-temperature phases revealed that the supramolecular π-π interactions between the spin-crossover Fe(qnal)2 cations as well as the cation contraction play an important role in the uniaxial lattice deformation which will modulate the electrical conductivity of the conducting Pd(dmit)2 layer.

本文言語English
ページ(範囲)6688-6689
ページ数2
ジャーナルJournal of the American Chemical Society
130
21
DOI
出版ステータスPublished - 2008 5 28

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

フィンガープリント

「Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system: [Fe<sup>III</sup>(qnal) <sub>2</sub>][Pd(dmit)<sub>2</sub>]<sub>5</sub>·acetone」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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