Extraordinary microwave effect on atropo-enantioselective catalytic reduction of biaryl lactones

Kazuya Nushiro, Satoshi Kikuchi, Tohru Yamada

研究成果: Review article

18 引用 (Scopus)

抜粋

It was found that microwave irradiation under strictly controlled temperature conditions drastically enhanced the catalytic atropo- enantioselective CoreyBakshiShibata (CBS) reduction of biaryl lactones. Since the high enantioselectivity was maintained completely compared with conventional heating conditions, the present enhancement is not caused by simple microwave heating. It was also revealed that the microwave irradiation could accelerate the racemization of the atropoenantiomers of optically active biaryl lactone. It could be concluded that the drastic enhancement with retention of the high enantioselectivity was caused not by simple heating, but by some direct microwave effect on the substrate molecule.

元の言語English
ページ(範囲)165-167
ページ数3
ジャーナルChemistry Letters
42
発行部数2
DOI
出版物ステータスPublished - 2013 2 21

ASJC Scopus subject areas

  • Chemistry(all)

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