Fabrication of layered hydroxide zinc nitrate films and their conversion to ZnO nanosheet assemblies for use in dye-sensitized solar cells

Takuya Yuki, Shintaro Ueno, Manabu Hagiwara, Shinobu Fujihara

研究成果: Article査読

12 被引用数 (Scopus)

抄録

Layered hydroxide zinc nitrate (LHZN; Zn 5 (NO 3 ) 2 (OH) 8 ·xH 2 O) films were fabricated on glass or plastic substrates by a chemical bath deposition method combined with a homogeneous precipitation in methanolic solutions. High- or low-temperature pyrolytic decomposition of the LHZN films having two-dimensional morphology was attempted to obtain porous ZnO nanosheet-assembly films. The LHZN films were converted into porous ZnO films by pyrolyzing at temperatures above 400°C, while porous LHZN/ZnO hybrid films were obtained by pyrolyzing at a lower temperature of 120°C without morphological changes. The pyrolyzed ZnO films were applied to dye-sensitized solar cells (DSSCs), resulting in the generation of relatively high open-circuit voltages. The low-temperature pyrolysis enabled us to fabricate the LHZN/ZnO film even on the plastic substrate. Actually a cell using the LHZN/ZnO film on an indium tin oxide-coated polyethylene naphthalate substrate showed an energy conversion efficiency of 2.08% with a high open-circuit voltage around 0.70V.

本文言語English
ページ(範囲)144-150
ページ数7
ジャーナルJournal of Asian Ceramic Societies
3
1
DOI
出版ステータスPublished - 2015 3月 1

ASJC Scopus subject areas

  • セラミックおよび複合材料

フィンガープリント

「Fabrication of layered hydroxide zinc nitrate films and their conversion to ZnO nanosheet assemblies for use in dye-sensitized solar cells」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル