Factors that stabilize the (dxz, dyz)3 (dxy)1 (dz2)1 electron configuration in iron(III) porphyrinates: A case of bis(benzaldehyde) complex

Akira Ikezaki, Yoshiki Ohgo, Taishi Watanabe, Mikio Nakamura

研究成果: Article

5 引用 (Scopus)

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Analysis of the 1H and 13C NMR chemical shifts has revealed that bis-ligated iron(III) porphyrinates, [Fe(Porphyrin)(L)2]±, adopt the (dxz, dyz)3 (dxy)1 (dz2)1 ground state if the complex has highly ruffled porphyrin core and carries weak oxygen ligand with multiple bond such as benzaldehyde.

元の言語English
ページ(範囲)1198-1201
ページ数4
ジャーナルInorganic Chemistry Communications
11
発行部数10
DOI
出版物ステータスPublished - 2008 10

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

フィンガープリント Factors that stabilize the (d<sub>xz</sub>, d<sub>yz</sub>)<sup>3</sup> (d<sub>xy</sub>)<sup>1</sup> (d<sub>z2</sub>)<sup>1</sup> electron configuration in iron(III) porphyrinates: A case of bis(benzaldehyde) complex' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

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