Analysis of the 1H and 13C NMR chemical shifts has revealed that bis-ligated iron(III) porphyrinates, [Fe(Porphyrin)(L)2]±, adopt the (dxz, dyz)3 (dxy)1 (dz2)1 ground state if the complex has highly ruffled porphyrin core and carries weak oxygen ligand with multiple bond such as benzaldehyde.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry