Formal total synthesis of altohyrtin C (spongistatin 2). Part 2: Construction of fully elaborated ABCD and EF fragments

Takeshi Terauchi, Taisaku Tanaka, Taro Terauchi, Masataka Morita, Kyoko Kimijima, Ippei Sato, Wataru Shoji, Yasuhiro Nakamura, Tomoharu Tsukada, Takashi Tsunoda, Gouichirou Hayashi, Naoki Kanoh, Masaya Nakata

研究成果: Article

25 引用 (Scopus)

抜粋

Coupling of the C1-C14 (AB) crotylstannane with the C15-C28 (CD) aldehyde followed by stereochemical arrangements gave the C1-C28 (ABCD) fragment of altohyrtin C. The C29-C44 (EF) fragment was also prepared. The syntheses of these two fragments, both of which were identical with those prepared by the Smith group, constitute a formal total synthesis of altohyrtin C.

元の言語English
ページ(範囲)7747-7751
ページ数5
ジャーナルTetrahedron Letters
44
発行部数42
DOI
出版物ステータスPublished - 2003 10 13

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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    Terauchi, T., Tanaka, T., Terauchi, T., Morita, M., Kimijima, K., Sato, I., Shoji, W., Nakamura, Y., Tsukada, T., Tsunoda, T., Hayashi, G., Kanoh, N., & Nakata, M. (2003). Formal total synthesis of altohyrtin C (spongistatin 2). Part 2: Construction of fully elaborated ABCD and EF fragments. Tetrahedron Letters, 44(42), 7747-7751. https://doi.org/10.1016/j.tetlet.2003.08.083