Formation and photoelectron spectroscopy of nanoscale cluster anions of biphenyl, (BP) n - (n = 2-100)

Masaaki Mitsui, Yukino Matsumoto, Naoto Ando, Atsushi Nakajima

研究成果: Article査読

5 被引用数 (Scopus)

抄録

Evolution of electronic structures of nanoscale biphenyl cluster anions, (BP) n - (n = 2-100), have been studied by photoelectron spectroscopy in a size-selective fashion. The energetics of vertical detachment energy (VDE) revealed negative electron affinity of a biphenyl molecule and substantial cluster reorganizations via electron attachment. Comparison of the VDE energetics with naphthalene cluster anions implied that the freezing (and/or melting) temperatures of the BP clusters may be much lower than those of naphthalene clusters.

本文言語English
論文番号CL-050831
ページ(範囲)1244-1245
ページ数2
ジャーナルChemistry Letters
34
9
DOI
出版ステータスPublished - 2005 9 5

ASJC Scopus subject areas

  • 化学 (全般)

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