Formation of vanadium-arene complex anions and their photoelectron spectroscopy

Ken Judai, Masaaki Hirano, Hiroshi Kawamata, Satoshi Yabushita, Atsushi Nakajima, Koji Kaya

研究成果: Article査読

66 被引用数 (Scopus)

抄録

Vanadium-arene complex anions, V1(arene)-m (m =1,2; arene = benzene, fluorobenzene, and toluene) were synthesized by the gas phase reaction of laser vaporized metal atoms with aromatic compound vapors. According to the 18-electron rule, it was anticipated that bis(benzene)vanadium should be stabilized by an electron attachment. However, it was experimentally concluded that bis(benzene)vanadium has negative electron affinity. The photoelectron spectra for the observed complex anions were measured, and the electronic configurations of metal-arene complexes and their structures are discussed.

本文言語English
ページ(範囲)23-30
ページ数8
ジャーナルChemical Physics Letters
270
1-2
DOI
出版ステータスPublished - 1997 5月 16

ASJC Scopus subject areas

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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