Generation of 2-substituted-2-metallo-1,3-dithianes and their coupling with 1,2-disubstituted epoxides at room temperature

Mitsuaki Ide, Minora Yasuda, Masaya Nakata

研究成果: Article査読

38 被引用数 (Scopus)

抄録

2-Substituted-1,3-dithianes were subjected to lithiation by n-BuLi at room temperature and the resulting anions reacted with 1,2-disubstituted epoxides at room temperature, giving the coupling products in satisfactory yield. In addition, a mixed organometallic reagent, n-BuLi/Bu2Mg, was found to be an effective metallation reagent for 2-substituted-1,3-dithianes.

本文言語English
ページ(範囲)936-938
ページ数3
ジャーナルSynlett
8
DOI
出版ステータスPublished - 1998 8

ASJC Scopus subject areas

  • Organic Chemistry

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