Glycosyl-Acceptor-Derived Borinic Ester-Promoted Direct and β-Stereoselective Mannosylation with a 1,2-Anhydromannose Donor

Masamichi Tanaka, Junki Nashida, Daisuke Takahashi, Kazunobu Toshima

研究成果: Article査読

51 被引用数 (Scopus)

抄録

β-Stereoselective mannosylations were conducted using a 1,2-anhydromannose donor and mono-ol acceptors in the presence of a glycosyl-acceptor-derived borinic ester. Reactions proceeded smoothly under mild conditions to provide the corresponding β-mannosides with high stereoselectivity in moderate to high yields. In addition, the present glycosylation method was applied successfully to the total synthesis of acremomannolipin A.

本文言語English
ページ(範囲)2288-2291
ページ数4
ジャーナルOrganic Letters
18
9
DOI
出版ステータスPublished - 2016 5 6

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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