Glycothermal synthesis and characterization of scheelite-type NaEuW 2 O8 nanophosphors

Ryo Kasuya, Tetsuhiko Isobe

研究成果: Article査読

2 被引用数 (Scopus)

抄録

Scheelite-type NaEuW2 O8 (NEW) nanophosphors were synthesized from a tungsten source and acetates of sodium and europium(III) in 1,4-butylene glycol by a glycothermal reaction. When dodecatungstophosphoric acid hexahydrate (DPA) was chosen as a tungsten source, a glycothermal reaction at temperatures ranging from 200 to 300°C produced crystalline NEW nanophosphors in a single phase. The tetrahedral PO4 unit derived from DPA plays a significant role in the formation of crystalline NEW. The photoluminescence intensity due to the 4f-4f transitions of Eu3+ for the sample prepared at 200°C was over 80 times higher than that of the sample prepared at 300°C. The amount of organic species, determined by thermogravimetry, for the former was three times larger than that of the latter. We therefore conclude that the effect of surface passivation predominantly enhances the photoluminescence intensity of the scheelite-type NEW nanophosphor.

本文言語English
ページ(範囲)J278-J282
ジャーナルJournal of the Electrochemical Society
156
9
DOI
出版ステータスPublished - 2009 8 7

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 再生可能エネルギー、持続可能性、環境
  • 表面、皮膜および薄膜
  • 電気化学
  • 材料化学

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