Grubbs carbene complex-catalyzed cleavage of allyl vic-diols to aldehydes with a co-oxidant: Application to the selective cleavage of huge marine molecules

Chunguang Han, Yoshi Yamano, Fumitoshi Kakiuchi, Kazuhiko Nakamura, Daisuke Uemura

研究成果: Article査読

9 被引用数 (Scopus)

抄録

An oxidative cleavage of allyl vic-diols to aldehydes catalyzed by a Grubbs carbene complex using a co-oxidant has been established for the first time, with good yields. The utility of this selective cleavage reaction was demonstrated through the use of two huge marine molecules, symbiodinolide and N-p-BrBz palytoxin.

本文言語English
ページ(範囲)9622-9626
ページ数5
ジャーナルTetrahedron
67
49
DOI
出版ステータスPublished - 2011 12 9

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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