Hexahydro-dibenz[d,f]azecines: Existence of Two Conformational Isomers of the 6-Oxo derivatives in Solution1)

Yoshisuke Tsuda, Masami Murata, Fumiyuki Kiuchi

研究成果: Article査読

7 被引用数 (Scopus)

抄録

New hexahydro-dibenz[d,f]azecines, 11 and 12, were synthesized from the homoerythrinan-enone 3. Their 6-oxo derivatives were shown to exist in two conformations in solution due to the rotational isomerism of the ten-membered lactam group. An example of remarkably large separation of two methylenedioxy protons in the proton nuclear magnetic resonance spectrum due to their non-equivalence is also presented.

本文言語English
ページ(範囲)3910-3914
ページ数5
ジャーナルChemical and Pharmaceutical Bulletin
34
9
DOI
出版ステータスPublished - 1986
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)
  • 創薬

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