Highly enantioselective borohydride reductions of 2-phenacylpyridine catalyzed by optically active β-ketoiminato cobalt(II) complexes

Yuhki Ohtsuka; Taketo Ikeno; Tohru Yamada

doi:10.1016/S0957-4166(00)00369-4

Highly enantioselective borohydride reductions of 2-phenacylpyridine catalyzed by optically active β-ketoiminato cobalt(II) complexes

Yuhki Ohtsuka, Taketo Ikeno, Tohru Yamada

化学科

研究成果: Article

16 引用（Scopus）

抜粋

The highly enantioselective reduction of 2-phenacylpyridine catalyzed by optically active β-ketoiminato cobalt(II) complexes with pre-modified sodium borohydride was achieved affording in high enantiomeric excess 1-phenyl-2-(2-pyridyl)ethanol, a precursor of sedamine derivatives. The enantioselective sense in the present reduction is discussed and compared to the asymmetric reduction catalyzed by other complex catalysts. Copyright (C) 2000 Elsevier Science Ltd.

元の言語	English
ページ（範囲）	3671-3674
ページ数	4
ジャーナル	Tetrahedron Asymmetry
巻	11
発行部数	18
DOI	https://doi.org/10.1016/S0957-4166(00)00369-4
出版物ステータス	Published - 2000 9 22

フィンガープリント

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

これを引用

Ohtsuka, Y., Ikeno, T., & Yamada, T. (2000). Highly enantioselective borohydride reductions of 2-phenacylpyridine catalyzed by optically active β-ketoiminato cobalt(II) complexes. Tetrahedron Asymmetry, 11(18), 3671-3674. https://doi.org/10.1016/S0957-4166(00)00369-4

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文献にアクセス

10.1016/S0957-4166(00)00369-4