TY - JOUR
T1 - Highly enantioselective borohydride reductions of 2-phenacylpyridine catalyzed by optically active β-ketoiminato cobalt(II) complexes
AU - Ohtsuka, Yuhki
AU - Ikeno, Taketo
AU - Yamada, Tohru
N1 - Copyright:
Copyright 2007 Elsevier B.V., All rights reserved.
PY - 2000/9/22
Y1 - 2000/9/22
N2 - The highly enantioselective reduction of 2-phenacylpyridine catalyzed by optically active β-ketoiminato cobalt(II) complexes with pre-modified sodium borohydride was achieved affording in high enantiomeric excess 1-phenyl-2-(2-pyridyl)ethanol, a precursor of sedamine derivatives. The enantioselective sense in the present reduction is discussed and compared to the asymmetric reduction catalyzed by other complex catalysts. Copyright (C) 2000 Elsevier Science Ltd.
AB - The highly enantioselective reduction of 2-phenacylpyridine catalyzed by optically active β-ketoiminato cobalt(II) complexes with pre-modified sodium borohydride was achieved affording in high enantiomeric excess 1-phenyl-2-(2-pyridyl)ethanol, a precursor of sedamine derivatives. The enantioselective sense in the present reduction is discussed and compared to the asymmetric reduction catalyzed by other complex catalysts. Copyright (C) 2000 Elsevier Science Ltd.
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U2 - 10.1016/S0957-4166(00)00369-4
DO - 10.1016/S0957-4166(00)00369-4
M3 - Article
AN - SCOPUS:0034703162
SN - 0957-4166
VL - 11
SP - 3671
EP - 3674
JO - Tetrahedron Asymmetry
JF - Tetrahedron Asymmetry
IS - 18
ER -