Highly enantioselective borohydride reductions of 2-phenacylpyridine catalyzed by optically active β-ketoiminato cobalt(II) complexes

Yuhki Ohtsuka, Taketo Ikeno, Tohru Yamada

研究成果: Article

16 引用 (Scopus)

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The highly enantioselective reduction of 2-phenacylpyridine catalyzed by optically active β-ketoiminato cobalt(II) complexes with pre-modified sodium borohydride was achieved affording in high enantiomeric excess 1-phenyl-2-(2-pyridyl)ethanol, a precursor of sedamine derivatives. The enantioselective sense in the present reduction is discussed and compared to the asymmetric reduction catalyzed by other complex catalysts. Copyright (C) 2000 Elsevier Science Ltd.

元の言語English
ページ(範囲)3671-3674
ページ数4
ジャーナルTetrahedron Asymmetry
11
発行部数18
DOI
出版物ステータスPublished - 2000 9 22

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ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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