Highly enantioselective borohydride reductions of 2-phenacylpyridine catalyzed by optically active β-ketoiminato cobalt(II) complexes

Yuhki Ohtsuka, Taketo Ikeno, Tohru Yamada

研究成果: Article査読

16 被引用数 (Scopus)

抄録

The highly enantioselective reduction of 2-phenacylpyridine catalyzed by optically active β-ketoiminato cobalt(II) complexes with pre-modified sodium borohydride was achieved affording in high enantiomeric excess 1-phenyl-2-(2-pyridyl)ethanol, a precursor of sedamine derivatives. The enantioselective sense in the present reduction is discussed and compared to the asymmetric reduction catalyzed by other complex catalysts. Copyright (C) 2000 Elsevier Science Ltd.

本文言語English
ページ(範囲)3671-3674
ページ数4
ジャーナルTetrahedron Asymmetry
11
18
DOI
出版ステータスPublished - 2000 9 22

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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