抄録
The highly enantioselective cyclopropanation of styrenes and diazoacetates proceeded in alcohol or aqueous alcohol in the presence of the β-ketoiminato cobalt(II) complex. Water and alcohols accelerated the reaction and improved the diastereo- and enantioselectivities. In these media, the α,α-disubstituted styrenes were smoothly cyclopropanated with high enantiomeric excess.
本文言語 | English |
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ページ(範囲) | 406-408 |
ページ数 | 3 |
ジャーナル | Synlett |
号 | 3 |
DOI | |
出版ステータス | Published - 2001 |
ASJC Scopus subject areas
- 有機化学