Highly Stereoselective [3+2] Cycloadditions of Nitrile Oxides to Methyl 4-O-Acryloyl-6-deoxy-2,3-O-(t-butyldimethylsilyl)-α-D-glucopyranoside

Tetsuo Tamai, Shingo Asano, Kiichiro Totani, Ken Ichi Takao, Kin Ichi Tadano

研究成果: Article査読

20 被引用数 (Scopus)

抄録

The [3+2] cycloadditions of benzonitrile oxide or pivalonitrile oxide to methyl 4-O-acryloyl-6-deoxy-2,3-di-O-(t-butyldimethylsilyl)-α -D-glucopyranoside provided the respective adducts, each as virtually a single diastereomer. By reductive removal of the carbohydrate template from each adduct, the respective (R)-enriched Δ2-isoxazoline derivative was obtained.

本文言語English
ページ(範囲)1865-1867
ページ数3
ジャーナルSynlett
12
DOI
出版ステータスPublished - 2003 1 1

ASJC Scopus subject areas

  • Organic Chemistry

フィンガープリント 「Highly Stereoselective [3+2] Cycloadditions of Nitrile Oxides to Methyl 4-O-Acryloyl-6-deoxy-2,3-O-(t-butyldimethylsilyl)-α-D-glucopyranoside」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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